|
|
NADP+ + dihydrobiochanin-A <=> NADPH + Biochanin_A + H+
|
1.3.1.46
biochanin-A reductase
|
–
|
K
|
| |
BRENDA:
BR36828
KEGG:
R02954
MetaCyc:
BIOCHANIN-A-REDUCTASE-RXN
|
|
|
|
S-adenosyl-L-methionine + genistein <=> H+ + Biochanin_A + S-adenosyl-L-homocysteine
|
2.1.1.155
kaempferol 4'-O-methyltransferase
2.1.1.212
2,7,4'-trihydroxyisoflavanone 4'-O-methyltransferase
2.1.1.231
flavonoid 4'-O-methyltransferase
2.1.1.46
isoflavone 4'-O-methyltransferase
|
–
–
–
–
|
MK
|
| |
BRENDA:
BS289635
KEGG:
R02931
MetaCyc:
RXN-3645
|
|
|
|
UDP-glucose + Biochanin_A <=> biochanin_A_7-O-beta-D-glucopyranoside + UDP
|
2.4.1.170
isoflavone 7-O-glucosyltransferase
|
–
|
MK
|
| |
BRENDA:
BS322255
KEGG:
R06795
MetaCyc:
RXN-4702
|
|
|
|
biochanin_A_7-O-beta-D-glucopyranoside + H2O <=> Biochanin_A + D-glucose + H+
|
3.2.1.161
beta-apiosyl-beta-glucosidase
3.2.1.21
beta-glucosidase
|
–
–
|
M
|
| |
BRENDA:
BS373214
MetaCyc:
RXN-4705
|
|
|
|
Biochanin_A + reduced_flavodoxin + O2 <=> Pratensein + flavin + H2O
|
1.14.14.88
isoflavone 3'-hydroxylase
|
–
|
K
|
| |
BRENDA:
BS186715
KEGG:
R07776
|
|
|
|
Biochanin_A + reduced_flavodoxin + O2 <=> 2''-hydroxybiochanin_A + flavin + H2O
|
1.14.14.89
4'-methoxyisoflavone 2'-hydroxylase
1.14.14.90
isoflavone 2'-hydroxylase
|
–
–
|
K
|
| |
BRENDA:
BS186718
KEGG:
R06561
|
|
|
|
Biochanin_A + O2 + reduced_[NADPH-hemoprotein_reductase] <=> Pratensein + oxidized_[NADPH-hemoprotein_reductase] + H2O
|
1.14.14.88
isoflavone 3'-hydroxylase
|
–
|
M
|
| |
MetaCyc:
RXN-3761
|
|
|
|
2,5,7-trihydroxy-4''-methoxyisoflavanone <=> Biochanin_A + H2O
|
not assigned
|
–
|
M
|
| |
MetaCyc:
RXN-5502
|
|
|
|
dimethylallyl_diphosphate + Biochanin_A <=> diphosphate + gancaonin_A
|
2.5.1.80
7-dimethylallyltryptophan synthase
|
–
|
|
| |
BRENDA:
BS423346
|
|
|
|
biochanin_A_7-O-[beta-D-apiofuranosyl-(1-6)-beta-D-glucopyranoside] + H2O <=> Biochanin_A + beta-D-apiofuranosyl-(1-6)-beta-D-glucopyranose
|
3.2.1.161
beta-apiosyl-beta-glucosidase
|
–
|
|
| |
BRENDA:
BS378643
|
|
|
|
UDP-glucuronate + Biochanin_A <=> UDP + biochanin_A_beta-D-glucuronide
|
2.4.1.17
glucuronosyltransferase
|
–
|
|
| |
BRENDA:
BS378104
|
|
|
|
Biochanin_A + H2O2 + I- <=> 6,8-diiodobiochanin_A + H2O
|
1.11.1.8
iodide peroxidase
|
–
|
|
| |
BRENDA:
BS289008
|
|
|
|
O2 + NADPH + H+ + Biochanin_A <=> H2O + 2''-Hydroxybiochanin_A + NADP+
|
1.14.14.90
isoflavone 2'-hydroxylase
|
–
|
|
| |
SABIO-RK:
6137
|
|
|
|
H+ + NADPH + O2 + Biochanin_A <=> H2O + NADP+ + 3''-Hydroxybiochanin_A
|
1.14.14.88
isoflavone 3'-hydroxylase
|
–
|
|
| |
SABIO-RK:
14151
|
|
